Ants should not be able to set off an ionization smoke detector.
Ant spray ( or hair spray for that matter) would.
If these are the hard wired home detectors you should be able to breaker them off, though you will likely get some other stuff you don't want off with them.
There *should* be a light indicator which shows which detector triggered the alarm and which ones are relaying. Assuming it was all installed correctly.
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