0% chance of that happening. It would certainly be cool to see a remastered version of some of the old (good) EA titles, but it won't happen.
The only way this happens is if the new college football game is itself a reskinned port of NCAA 14, but I would bet my house that won't happen.
NCAA 14 uses an entirely different engine than what EA uses for all of their other sports titles at this point. So, to make a NCAA 14 then they would need a separate development team to build this (on top of the one building the new game), and there were need to be a financial incentive to do so which would be really difficult to justify when they already have an engine for other sports titles. Plus it would be a very niche market to sell to given that it's a 10 year old sports game. More expense and less potential revenue.
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