I'd say the top two easily would be Brad Pitt and Oprah Winfrey. Pitt is probably one of the more down to earth "mega stars" out there. The guy apparently has no problem taking all of his kids to the movies, ball games, etc. and generally acting like a "normal guy". He personally donated 5 million dollars to help rebuild homes for Katrina Victims and is involved with all kinds of different African aid foundations, etc.
Oprah...well obviously she gives a TON as well. I think the ultimate show of unselfishness was when she bought every member of her audience a freaking car! She gives away homes like they are party favors and is generally thought of as an "uber-humanitarian".
Any others? For all the mega bucks most celebrities make, it's easy to forget that some of them give away fortunes in the name of goodwill, etc.
I just saw an interview with Pitt and it got me to thinking about this topic.

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