Just keep it simple for yourself. It took me most of my first playthrough to really start getting all the potions and I still forget some of what's available.
It's as overwhelming as you let it be. You can keep the game simple by focusing on just a few signs, potions, etc. or you can dig deep and use everything available to you.. it's all about how you want to approach the game. There are a few situations where the game basically walks you by hand through a particular necessary potion, though.
Don't get discouraged yet...

The branching (glyph?) tree within the options menu, the one where you spend upgrade points, I do use. Other than that I can't recall the last time I've used any of the potions to assist in battles.
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